Nicolaas Vermeulen

Northwestern University, University of Illinois at Urbana-Champaign

Research Expertise

Organic Chemistry

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Publications

Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks
Chemistry of Materials
2016
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
Journal of the American Chemical Society
2014
An artificial molecular pump
Nature Nanotechnology
2015
Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
Journal of the American Chemical Society
2015
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000
Nature Protocols
2015
Bottom-up construction of a superstructure in a porous uranium-organic crystal
Science
2017
Hierarchically Engineered Mesoporous Metal-Organic Frameworks toward Cell-free Immobilized Enzyme Systems
Chem
2018
CD-MOF: A Versatile Separation Medium
Journal of the American Chemical Society
2016
In silico discovery of metal-organic frameworks for precombustion CO 2 capture using a genetic algorithm
Science Advances
2016
An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation
Journal of the American Chemical Society
2016
ChemInform Abstract: Supramolecular Explorations: Exhibiting the Extent of Extended Cationic Cyclophanes
ChemInform
2016
Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores
Angewandte Chemie
2016
Presence versus Proximity: The Role of Pendant Amines in the Catalytic Hydrolysis of a Nerve Agent Simulant
Angewandte Chemie International Edition
2018
A Hafnium-Based Metal–Organic Framework as a Nature-Inspired Tandem Reaction Catalyst
Journal of the American Chemical Society
2015
Aerobic Linear Allylic C–H Amination: Overcoming Benzoquinone Inhibition
Journal of the American Chemical Society
2016
ExCage
Journal of the American Chemical Society
2014
Pillar[5]arene as a Co-Factor in Templating Rotaxane Formation
Journal of the American Chemical Society
2013
The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol
Tetrahedron
2009
Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework
Angewandte Chemie International Edition
2018
Synthesis of Complex Allylic Esters via C−H Oxidation vs C−C Bond Formation
Journal of the American Chemical Society
2010
Rendering High Surface Area, Mesoporous Metal–Organic Frameworks Electronically Conductive
ACS Applied Materials & Interfaces
2017
Non-Interpenetrated Metal–Organic Frameworks Based on Copper(II) Paddlewheel and Oligoparaxylene-Isophthalate Linkers: Synthesis, Structure, and Gas Adsorption
Journal of the American Chemical Society
2016
Synthesis of ExnBox Cyclophanes
The Journal of Organic Chemistry
2013
Ex2Box: Interdependent Modes of Binding in a Two-Nanometer-Long Synthetic Receptor
Journal of the American Chemical Society
2013
A metal–organic framework immobilised iridium pincer complex
Chemical Science
2016
Polyol Synthesis through Hydrocarbon Oxidation: De Novo Synthesis of L‐Galactose
Angewandte Chemie
2006
Modulating the Binding of Polycyclic Aromatic Hydrocarbons Inside a Hexacationic Cage by Anion–π Interactions
Angewandte Chemie International Edition
2014
Energetically Demanding Transport in a Supramolecular Assembly
Journal of the American Chemical Society
2014
Aromatizing Olefin Metathesis by Ligand Isolation inside a Metal– Organic Framework
Journal of the American Chemical Society
2013
Energy and Electron Transfer Dynamics within a Series of Perylene Diimide/Cyclophane Systems
Journal of the American Chemical Society
2015
Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation
European Journal of Inorganic Chemistry
2016
Functionalized Defects through Solvent-Assisted Linker Exchange: Synthesis, Characterization, and Partial Postsynthesis Elaboration of a Metal–Organic Framework Containing Free Carboxylic Acid Moieties
Inorganic Chemistry
2015
Effect of Redox “Non-Innocent” Linker on the Catalytic Activity of Copper-Catecholate-Decorated Metal–Organic Frameworks
ACS Applied Materials & Interfaces
2017
A visually detectable pH responsive zirconium metal–organic framework
Chemical Communications
2016
Gated Electron Sharing Within Dynamic Naphthalene Diimide‐Based Oligorotaxanes
Angewandte Chemie International Edition
2014
Ultrafast Two-Electron Transfer in a CdS Quantum Dot–Extended-Viologen Cyclophane Complex
Journal of the American Chemical Society
2016
Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal–Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer
ACS Applied Materials & Interfaces
2016
An ExBox [2]catenane
Chemical Science
2014
The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification
Journal of the American Chemical Society
2019
Towards hydroxamic acid linked zirconium metal–organic frameworks
Materials Chemistry Frontiers
2017
Allosteric Modulation of Substrate Binding within a Tetracationic Molecular Receptor
Journal of the American Chemical Society
2015
SALE‐Ing a MOF‐Based “Ship of Theseus.” Sequential Building‐Block Replacement for Complete Reformulation of a Pillared‐Paddlewheel Metal‐Organic Framework
European Journal of Inorganic Chemistry
2016
Catenation through a Combination of Radical Templation and Ring-Closing Metathesis
Journal of the American Chemical Society
2015
Liquid‐Phase Epitaxially Grown Metal–Organic Framework Thin Films for Efficient Tandem Catalysis Through Site‐Isolation of Catalytic Centers
ChemPlusChem
2016
Aerobic Allylation of Alcohols with Non-Activated Alkenes Enabled by Light-Driven Selenium-π-Acid Catalysis
Synthesis
2018
Magnetic Control of MOF Crystal Orientation and Alignment
Chemistry – A European Journal
2017
Formation of a hetero[3]rotaxane by a dynamic component-swapping strategy
Chem. Commun.
2014
Cooperative Reactivity in an Extended-Viologen-Based Cyclophane
Journal of the American Chemical Society
2016
Surviving Under Pressure: The Role of Solvent, Crystal Size, and Morphology During Pelletization of Metal–Organic Frameworks
ACS Applied Materials & Interfaces
2021
Isomerization and Selective Hydrogenation of Propyne: Screening of Metal–Organic Frameworks Modified by Atomic Layer Deposition
Journal of the American Chemical Society
2020
Influence of spin state and electron configuration on the active site and mechanism for catalytic hydrogenation on metal cation catalysts supported on NU-1000: insights from experiments and microkinetic modeling
Catalysis Science & Technology
2020
Extending the Compositional Range of Nanocasting in the Oxozirconium Cluster-Based Metal–Organic Framework NU-1000—A Comparative Structural Analysis
Chemistry of Materials
2018
Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size
Organic Materials
2020
NHPI- and TBAI-Co-Catalyzed Synthesis of Allylic Esters from Toluene Derivatives and Alkenes
Synlett
2018
The Allylic Acetoxylation of 1,1-Disubstituted Alkenes Catalyzed by a Palladium(II)/Monothiadiazole Ligand System
Synlett
2019
Correction to “A Hafnium-Based Metal–Organic Framework as a Nature-Inspired Tandem Reaction Catalyst”
Journal of the American Chemical Society
2016
Self-Assembly of Two Tubular Metalloligand-Based PalladiumOrganic Cages as Hosts for Polycyclic Aromatic Hydrocarbons
Unknown Venue
Cracking
Unknown Venue
2024
Palladium-Catalyzed Oxidative Allylic Alkylation of N-Hydroxy­imides
Synlett
2019
Sinter‐Resistant Platinum Catalyst Supported by Metal–Organic Framework
Angewandte Chemie
2018
Front Cover: Adding to the Arsenal of Zirconium‐Based Metal–Organic Frameworks: the Topology as a Platform for Solvent‐Assisted Metal Incorporation (Eur. J. Inorg. Chem. 27/2016)
European Journal of Inorganic Chemistry
2016
Gated Electron Sharing Within Dynamic Naphthalene Diimide‐Based Oligorotaxanes
Angewandte Chemie
2014
Pillararene-related Macrocycles
Pillararenes
2015
Planning for Emerging Mobility: Testing and Deployment in Illinois
Unknown Venue
2023
Hydrocarbon Oxidation vs C-C Bond-Forming Approaches for Efficient Syntheses of Oxygenated Molecules
Unknown Venue
Total Synthesis of Protected l-Galactose by Hydrocarbon Oxidation
Synfacts
2007
ChemInform Abstract: Aerobic Linear Allylic C—H Amination: Overcoming Benzoquinone Inhibition.
ChemInform
2016
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